David Roth is a Chemist with the USGS Water Resources Mission Area and Integrated Water Chemistry Assessment Laboratory.
Science and Products
Total mercury, bulk density, percent organic matter, and percent organic carbon measured in permafrost cores from the interior and northern slope of Alaska and previously published studies
This data release contains two datasets (see child items below). The first dataset, "MasterDB-csv-published-final.csv", includes 11,000 published measurements of sediment total mercury (STHg, nanograms per gram of soil, dry), bulk density (BD, grams per cm3 of soil, dry), percent of soil organic matter (%OM, loss on ignition, LOI), percent of soil organic carbon (%SOC, calculated using
Diel and synoptic sampling data from Boulder Creek and South Boulder Creek, near Boulder, Colorado, September–October 2019
Multiple sampling campaigns were conducted near Boulder, Colorado, to quantify constituent concentrations and loads in Boulder Creek and its tributary, South Boulder Creek. Diel sampling was initiated at approximately 1100 hours on September 17, 2019, and continued until approximately 2300 hours on September 18, 2019. During this time period, samples were collected at two locations on Boulder Cree
Target-Chemical Concentrations and Microbiological Results for Assessment of Mixed Contaminant and Biological Exposures in Bottled Water, 2020
This data release contains concentration and quality-assurance results for inorganic, organic analytes and microbiological pathogens collected from 30 different commercial bottled water sources. Samples were processed on July 20 and August 17, 2020 at the New Jersey Water Science Center and analyzed at various U.S. Geological Survey laboratories. Samples were analyzed for nutrients, cations and an
Water-Chemistry and Isotope Data for Selected Springs, Geysers, Streams, and Rivers in Yellowstone National Park, Wyoming
There are over 10,000 hydrothermal features in Yellowstone National Park (YNP), where waters have pH values ranging from about 1 to 10 and surface temperatures up to 95 °C. Active geothermal areas in YNP provide insight into a variety of processes occurring at depth, such as water-rock and oxidation-reduction (redox) reactions, the formation of alteration minerals, and microbial (thermophile)
Water-quality results from a wastewater reuse study: Inorganic and organic compositions of wastewater effluent and select urban and agricultural water types during rain-induced runoff, Chickasha, Oklahoma, 2018-2019
Oklahoma State University South-Central Research Station (SCRS) was used to conduct research to understand the chemical composition of various water types and their potential environmental and human health effects. The study area provided the opportunity to study five water types: (1) receiving surface water (Washita River), (2) urban stormwater, (3) wastewater treatment plant effluent used for ir
Streamflow and water chemistry in the Tenaya Lake Basin, Yosemite National Park, California
The Tenaya Lake Water Budget Study seeks to quantify and understand the water balance within the principal snow accumulation and runoff yielding zone in the Sierra Nevada Mountains. The Study operates stage sensors and data loggers to record Tenaya Lake inflows, water surface elevation, and outflow, with continuous annual data collection for the 21 square-kilometer watershed located in the alpine
Water quality of samples collected in the Russian River Watershed (2017-2019)
The Russian River watershed is an important resource for drinking water and recreation. Sonoma Water relies on the Russian River to provide drinking water to over 620,000 Sonoma County and Marin, CA residents. Nearly 1 million visitors enjoy numerous recreational opportunities on the Russian River annually. Wildfires have increased in frequency and intensity in Northern California and research is
Groundwater chemistry in the Lower East Rift Zone and summit of Kilauea Volcano, Hawai'i
Chemical and isotopic analyses are reported for water samples collected from water supply wells, a geothermal well in the Puna Geothermal Venture (PGV) power plant, a hot spring in the Puna District, a research well on the summit of Kilauea Volcano (informally called "NSF Well", or "Keller Well "), and a water catchment in the headquarters area of Hawai'i Volcanoes National Park, Hawai'i. These wa
Geochemical, mineralogical, and grain-size data for in-situ solid materials and suspended sediment at Malakoff Diggins State Historic Park, Nevada County, California
This dataset includes data for in-situ solid materials and suspended sediments from surface-water samples, as well as surface-water chemistry from samples collected during storm events at Malakoff Diggins State Historic Park, Nevada County, California. In-situ solid samples were collected during 2015 along six vertical transects along the cliff walls of the mine pit. Surface-water samples were col
Water chemistry data for selected hot springs and rivers in Southwest Yellowstone National Park, Wyoming
Water analyses are reported for 66 samples collected from numerous thermal and non-thermal (rivers and streams) features in the southwestern areas of Yellowstone National Park (YNP) during 2009, 2017, and 2018. Water samples were collected from sources near Boundary Creek, Bechler River, Falls River, Mountain Ash Creek, Upper Snake River, Spirea Creek, and Lewis Lake. These water samples were coll
Assessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic c
Survey of major and trace elements in stormwater runoff from across the United States, 2016 to 2017
This study focuses on providing a broad-scale assessment of composition of water chemistry in urban stormwater runoff. The stormwater runoff is a source of recharge to groundwater by Green Infrastructure (GI) practices or it may become a source of recharge to groundwater to reduce stormwater volumes to surface waters or augment groundwater supply. The chemical composition of the stormwater runoff
Filter Total Items: 18
Contaminant exposure and transport from three potential reuse waters within a single watershed
Global demand for safe and sustainable water supplies necessitates a better understanding of contaminant exposures in potential reuse waters. In this study, we compared exposures and load contributions to surface water from the discharge of three reuse waters (wastewater effluent, urban stormwater, and agricultural runoff). Results document substantial and varying organic-chemical contribution to
By
Water Resources, Environmental Health Program, California Water Science Center, Oklahoma Water Science Center, Central Midwest Water Science Center, Colorado Water Science Center, Geology, Energy & Minerals Science Center, Kansas Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, Reston Biogeochemical Processes in Groundwater Laboratory
The source, fate, and transport of arsenic in the Yellowstone hydrothermal system - An overview
The Yellowstone Plateau Volcanic Field (YPVF) contains >10,000 thermal features including hot springs, pools, geysers, mud pots, and fumaroles with diverse chemical compositions. Arsenic (As) concentrations in YPVF thermal waters typically range from 0.005 to 4 mg/L, but an As concentration of 17 mg/L has been reported. Arsenic data from thermal springs, outflow drainages, rivers, and from volcani
Bottled water contaminant exposures and potential human effects
Bottled water (BW) consumption in the United States and globally has increased amidst heightened concern about environmental contaminant exposures and health risks in drinking water supplies, despite a paucity of directly comparable, environmentally-relevant contaminant exposure data for BW. This study provides insight into exposures and cumulative risks to human health from inorganic/organic/micr
Watershed-scale risk to aquatic organisms from complex chemical mixtures in the Shenandoah River
River waters contain complex chemical mixtures derived from natural and anthropogenic sources. Aquatic organisms are exposed to the entire chemical composition of the water, resulting in potential effects at the organismal through ecosystem level. This study applied a holistic approach to assess landscape, hydrological, chemical, and biological variables. On-site mobile laboratory experiments were
Sources, fate, and flux of riverine solutes in the Southwest Yellowstone Plateau Volcanic Field, USA
Since the 1970s, temporal variations of hydrothermal discharge and thermal output from the numerous hydrothermal features in the Yellowstone Plateau Volcanic Field (YPVF) have been studied by measuring the chloride flux in the major rivers. In this study, the sources, fate, and flux of solutes in the Fall River and its major tributaries, in southwest Yellowstone National Park, were determined. The
Hydrothermal activity in the southwest Yellowstone Plateau Volcanic Field
In the past two decades, the U.S. Geological Survey and the National Park Service have studied hydrothermal activity across the Yellowstone Plateau Volcanic Field (YPVF) to improve the understanding of the magmatic-hydrothermal system and to provide a baseline for detecting future anomalous activity. In 2017 and 2018 we sampled water and gas over a large area in the southwest YPVF and used Landsat
Sources, fate, and flux of geothermal solutes in the Yellowstone and Gardner Rivers, Yellowstone National Park, WY
The total discharge and thermal output from the numerous hydrothermal features in Yellowstone National Park (YNP) can be estimated from the chloride (Cl) flux in the Madison, Yellowstone, Falls, and Snake Rivers. Monitoring the Cl flux in these four major rivers provides a holistic view of the hydrothermal output from YNP and changes in the Cl flux may indicate changes in geothermal or magmatic ac
Coagulant and sorbent efficacy in removing mercury from surface waters in the Cache Creek watershed, California
Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. E
Geochemical data for water, streambed sediment, and fish tissue from the Sierra Nevada Mercury Impairment Project, 2011–12
This report presents geochemical data for surface water, streambed sediment, and fish tissue samples collected during low-flow conditions in 20 to 24 Sierra Nevada streams during 2011 and 2012. The dataset is part of a larger study designed to assess the factors that control mercury concentrations in fish tissue and to develop a model that predicts mercury concentration in the tissue of selected f
Permafrost stores a globally significant amount of mercury
Changing climate in northern regions is causing permafrost to thaw with major implications for the global mercury (Hg) cycle. We estimated Hg in permafrost regions based on in situ measurements of sediment total mercury (STHg), soil organic carbon (SOC), and the Hg to carbon ratio (RHgC) combined with maps of soil carbon. We measured a median STHg of 43 ± 30 ng Hg g soil−1 and a median RHgC of 1.6
Effects of an extreme flood on trace elements in river water—From urban stream to major river basin
Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the Sou
Selected trace elements in the Sacramento River, California: Occurrence and distribution
The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements—including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium,
Science and Products
- Data
Total mercury, bulk density, percent organic matter, and percent organic carbon measured in permafrost cores from the interior and northern slope of Alaska and previously published studies
This data release contains two datasets (see child items below). The first dataset, "MasterDB-csv-published-final.csv", includes 11,000 published measurements of sediment total mercury (STHg, nanograms per gram of soil, dry), bulk density (BD, grams per cm3 of soil, dry), percent of soil organic matter (%OM, loss on ignition, LOI), percent of soil organic carbon (%SOC, calculated usingDiel and synoptic sampling data from Boulder Creek and South Boulder Creek, near Boulder, Colorado, September–October 2019
Multiple sampling campaigns were conducted near Boulder, Colorado, to quantify constituent concentrations and loads in Boulder Creek and its tributary, South Boulder Creek. Diel sampling was initiated at approximately 1100 hours on September 17, 2019, and continued until approximately 2300 hours on September 18, 2019. During this time period, samples were collected at two locations on Boulder CreeTarget-Chemical Concentrations and Microbiological Results for Assessment of Mixed Contaminant and Biological Exposures in Bottled Water, 2020
This data release contains concentration and quality-assurance results for inorganic, organic analytes and microbiological pathogens collected from 30 different commercial bottled water sources. Samples were processed on July 20 and August 17, 2020 at the New Jersey Water Science Center and analyzed at various U.S. Geological Survey laboratories. Samples were analyzed for nutrients, cations and anWater-Chemistry and Isotope Data for Selected Springs, Geysers, Streams, and Rivers in Yellowstone National Park, Wyoming
There are over 10,000 hydrothermal features in Yellowstone National Park (YNP), where waters have pH values ranging from about 1 to 10 and surface temperatures up to 95 °C. Active geothermal areas in YNP provide insight into a variety of processes occurring at depth, such as water-rock and oxidation-reduction (redox) reactions, the formation of alteration minerals, and microbial (thermophile)Water-quality results from a wastewater reuse study: Inorganic and organic compositions of wastewater effluent and select urban and agricultural water types during rain-induced runoff, Chickasha, Oklahoma, 2018-2019
Oklahoma State University South-Central Research Station (SCRS) was used to conduct research to understand the chemical composition of various water types and their potential environmental and human health effects. The study area provided the opportunity to study five water types: (1) receiving surface water (Washita River), (2) urban stormwater, (3) wastewater treatment plant effluent used for irStreamflow and water chemistry in the Tenaya Lake Basin, Yosemite National Park, California
The Tenaya Lake Water Budget Study seeks to quantify and understand the water balance within the principal snow accumulation and runoff yielding zone in the Sierra Nevada Mountains. The Study operates stage sensors and data loggers to record Tenaya Lake inflows, water surface elevation, and outflow, with continuous annual data collection for the 21 square-kilometer watershed located in the alpineWater quality of samples collected in the Russian River Watershed (2017-2019)
The Russian River watershed is an important resource for drinking water and recreation. Sonoma Water relies on the Russian River to provide drinking water to over 620,000 Sonoma County and Marin, CA residents. Nearly 1 million visitors enjoy numerous recreational opportunities on the Russian River annually. Wildfires have increased in frequency and intensity in Northern California and research isGroundwater chemistry in the Lower East Rift Zone and summit of Kilauea Volcano, Hawai'i
Chemical and isotopic analyses are reported for water samples collected from water supply wells, a geothermal well in the Puna Geothermal Venture (PGV) power plant, a hot spring in the Puna District, a research well on the summit of Kilauea Volcano (informally called "NSF Well", or "Keller Well "), and a water catchment in the headquarters area of Hawai'i Volcanoes National Park, Hawai'i. These waGeochemical, mineralogical, and grain-size data for in-situ solid materials and suspended sediment at Malakoff Diggins State Historic Park, Nevada County, California
This dataset includes data for in-situ solid materials and suspended sediments from surface-water samples, as well as surface-water chemistry from samples collected during storm events at Malakoff Diggins State Historic Park, Nevada County, California. In-situ solid samples were collected during 2015 along six vertical transects along the cliff walls of the mine pit. Surface-water samples were colWater chemistry data for selected hot springs and rivers in Southwest Yellowstone National Park, Wyoming
Water analyses are reported for 66 samples collected from numerous thermal and non-thermal (rivers and streams) features in the southwestern areas of Yellowstone National Park (YNP) during 2009, 2017, and 2018. Water samples were collected from sources near Boundary Creek, Bechler River, Falls River, Mountain Ash Creek, Upper Snake River, Spirea Creek, and Lewis Lake. These water samples were collAssessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic cSurvey of major and trace elements in stormwater runoff from across the United States, 2016 to 2017
This study focuses on providing a broad-scale assessment of composition of water chemistry in urban stormwater runoff. The stormwater runoff is a source of recharge to groundwater by Green Infrastructure (GI) practices or it may become a source of recharge to groundwater to reduce stormwater volumes to surface waters or augment groundwater supply. The chemical composition of the stormwater runoff - Publications
Filter Total Items: 18
Contaminant exposure and transport from three potential reuse waters within a single watershed
Global demand for safe and sustainable water supplies necessitates a better understanding of contaminant exposures in potential reuse waters. In this study, we compared exposures and load contributions to surface water from the discharge of three reuse waters (wastewater effluent, urban stormwater, and agricultural runoff). Results document substantial and varying organic-chemical contribution toByWater Resources, Environmental Health Program, California Water Science Center, Oklahoma Water Science Center, Central Midwest Water Science Center, Colorado Water Science Center, Geology, Energy & Minerals Science Center, Kansas Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, Reston Biogeochemical Processes in Groundwater LaboratoryThe source, fate, and transport of arsenic in the Yellowstone hydrothermal system - An overview
The Yellowstone Plateau Volcanic Field (YPVF) contains >10,000 thermal features including hot springs, pools, geysers, mud pots, and fumaroles with diverse chemical compositions. Arsenic (As) concentrations in YPVF thermal waters typically range from 0.005 to 4 mg/L, but an As concentration of 17 mg/L has been reported. Arsenic data from thermal springs, outflow drainages, rivers, and from volcaniBottled water contaminant exposures and potential human effects
Bottled water (BW) consumption in the United States and globally has increased amidst heightened concern about environmental contaminant exposures and health risks in drinking water supplies, despite a paucity of directly comparable, environmentally-relevant contaminant exposure data for BW. This study provides insight into exposures and cumulative risks to human health from inorganic/organic/micrWatershed-scale risk to aquatic organisms from complex chemical mixtures in the Shenandoah River
River waters contain complex chemical mixtures derived from natural and anthropogenic sources. Aquatic organisms are exposed to the entire chemical composition of the water, resulting in potential effects at the organismal through ecosystem level. This study applied a holistic approach to assess landscape, hydrological, chemical, and biological variables. On-site mobile laboratory experiments wereSources, fate, and flux of riverine solutes in the Southwest Yellowstone Plateau Volcanic Field, USA
Since the 1970s, temporal variations of hydrothermal discharge and thermal output from the numerous hydrothermal features in the Yellowstone Plateau Volcanic Field (YPVF) have been studied by measuring the chloride flux in the major rivers. In this study, the sources, fate, and flux of solutes in the Fall River and its major tributaries, in southwest Yellowstone National Park, were determined. TheHydrothermal activity in the southwest Yellowstone Plateau Volcanic Field
In the past two decades, the U.S. Geological Survey and the National Park Service have studied hydrothermal activity across the Yellowstone Plateau Volcanic Field (YPVF) to improve the understanding of the magmatic-hydrothermal system and to provide a baseline for detecting future anomalous activity. In 2017 and 2018 we sampled water and gas over a large area in the southwest YPVF and used LandsatSources, fate, and flux of geothermal solutes in the Yellowstone and Gardner Rivers, Yellowstone National Park, WY
The total discharge and thermal output from the numerous hydrothermal features in Yellowstone National Park (YNP) can be estimated from the chloride (Cl) flux in the Madison, Yellowstone, Falls, and Snake Rivers. Monitoring the Cl flux in these four major rivers provides a holistic view of the hydrothermal output from YNP and changes in the Cl flux may indicate changes in geothermal or magmatic acCoagulant and sorbent efficacy in removing mercury from surface waters in the Cache Creek watershed, California
Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. EGeochemical data for water, streambed sediment, and fish tissue from the Sierra Nevada Mercury Impairment Project, 2011–12
This report presents geochemical data for surface water, streambed sediment, and fish tissue samples collected during low-flow conditions in 20 to 24 Sierra Nevada streams during 2011 and 2012. The dataset is part of a larger study designed to assess the factors that control mercury concentrations in fish tissue and to develop a model that predicts mercury concentration in the tissue of selected fPermafrost stores a globally significant amount of mercury
Changing climate in northern regions is causing permafrost to thaw with major implications for the global mercury (Hg) cycle. We estimated Hg in permafrost regions based on in situ measurements of sediment total mercury (STHg), soil organic carbon (SOC), and the Hg to carbon ratio (RHgC) combined with maps of soil carbon. We measured a median STHg of 43 ± 30 ng Hg g soil−1 and a median RHgC of 1.6Effects of an extreme flood on trace elements in river water—From urban stream to major river basin
Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the SouSelected trace elements in the Sacramento River, California: Occurrence and distribution
The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements—including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium, - News