Science and Products
Data for volatile organic compounds in groundwater used for public supply across the United States, 2013-19, and data for associated quality-control samples
This data release includes tables and time-series plots of results for volatile organic compounds (VOCs) analyzed in samples of groundwater used for public supply that were collected by the USGS National Water-Quality Assessment (NAWQA) Project and the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) during 201
Data set for a mesocosm to field assessment of the ecological risks associated with neonicotinoids in US streams
Neonicotinoids, a widely used class of insecticide, have been found in surface waters globally. They pose a risk to non-target species found in aquatic environments such as aquatic macroinvertebrates. To better understand the effects of the neonicotinoids imidacloprid, clothianidin and their mixtures on aquatic communities we ran a 30 day mesocosm test. Rock trays were colonized with natural benth
Data set for an ecological risk assessment of Firpronil compounds in US streams
The phenylpyrazole insecticide fipronil and its degradates are a potential surface-water contaminant and toxicant to nontarget species such as aquatic macroinvertebrates. To better understand how fipronil, fipronil sulfide, fipronil sulfone, desulfinyl fipronil, and fipronil amide affect aquatic communities, a 30-day mesocosm experiment was run. Rock trays were colonized with natural benthic commu
Dissolved Pesticides in Weekly Water Samples from the NAWQA Regional Stream Quality Assessments (2013-2017)
Dissolved pesticides were measured in weekly water samples from 482 wadeable streams in five regions of the United States during 2013-2017, as part of the U.S. Geological Survey's (USGS) Regional Stream Quality Assessment (RSQA). One study was conducted each year, starting with the Midwest (2013), followed by the Southeast Piedmont (2014), Pacific Northwest (2015), Northeast (2016), and Central Ca
Field, laboratory, and third-party data for assessment of the quality of pesticide results reported by the National Water Quality Laboratory for groundwater samples collected by the National Water-Quality Assessment Project, 2013-18
This data release includes tables and plots of results for pesticide compounds (pesticides and degradates) analyzed in groundwater samples collected by the USGS National Water-Quality Assessment Project during water years 2013-18 and in associated quality-control samples that are used to assess the quality of the reported pesticide results. All samples were analyzed by the USGS National Water Qual
Supporting Data: Complex Mixtures of Pesticides in Midwest U.S. Streams Indicated by POCIS Time-Integrating Samplers
The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest fo
Filter Total Items: 53
Ecological consequences of neonicotinoid mixtures in streams
Neonicotinoid mixtures are common in streams worldwide, but corresponding ecological responses are poorly understood. We combined experimental and observational studies to narrow this knowledge gap. The mesocosm experiment determined that concentrations of the neonicotinoids imidacloprid and clothianidin (range of exposures, 0 to 11.9 μg/liter) above the hazard concentration for 5% of species (0.0
Authors
Travis S. Schmidt, Janet L. Miller, Barbara Mahler, Peter C. Van Metre, Lisa H. Nowell, Mark W. Sandstrom, Daren Carlisle, Patrick W. Moran, Paul Bradley
Food, beverage, and feedstock processing facility wastewater: A unique and underappreciated source of contaminants to U.S. streams
Process wastewaters from food, beverage, and feedstock facilities, although regulated, are an under-investigated environmental contaminant source. Food process wastewaters (FPWWs) from 23 facilities in 17 U.S. states were sampled and documented for a plethora of chemical and microbial contaminants. Of the 576 analyzed organics, 184 (32%) were detected at least once, with concentrations as large as
Authors
Laura E. Hubbard, Dana W. Kolpin, Carrie E Givens, Bradley D. Blackwell, Paul Bradley, James L. Gray, Rachael F. Lane, Jason R. Masoner, R. Blaine McCleskey, Kristin Romanok, Mark W. Sandstrom, Kelly Smalling, Daniel L. Villeneuve
By
Ecosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, Central Midwest Water Science Center, Kansas Water Science Center, New Jersey Water Science Center, Pennsylvania Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, National Water Quality Laboratory
New-generation pesticides are prevalent in California's Central Coast streams
Pesticides are widely recognized as important biological stressors in streams, especially in heavily developed urban and agricultural areas like the Central California Coast region. We assessed occurrence and potential toxicity of pesticides in small streams in the region using two analytical methods: a broad-spectrum (223 compounds) method in use since 2012 and a newly developed method for 30 add
Authors
Mark W. Sandstrom, Lisa H. Nowell, Barbara Mahler, Peter C. Van Metre
Inclusion of pesticide transformation products is key to estimating pesticide exposures and effects in small U.S. streams
Improved analytical methods can quantify hundreds of pesticide transformation products (TPs), but understanding of TP occurrence and potential toxicity in aquatic ecosystems remains limited. We quantified 108 parent pesticides and 116 TPs in more than 3 700 samples from 442 small streams in mostly urban basins across five major regions of the United States. TPs were detected nearly as frequently a
Authors
Barbara Mahler, Lisa H. Nowell, Mark W. Sandstrom, Paul Bradley, Kristin Romanok, Christopher Konrad, Peter Van Metre
By
Ecosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, New Jersey Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Washington Water Science Center, National Water Quality Laboratory
Comparison of detection limits estimated using single- and multi-concentration spike-based and blank-based procedures
Spike- and blank-based procedures were applied to estimate the detection limits (DLs) for example analytes from inorganic and organic methods for water samples to compare with the U.S. Environmental Protection Agency's (EPA) Method Detection Limit (MDL) procedures (revisions 1.11 and 2.0). The multi-concentration spike-based procedures ASTM Within-laboratory Critical Level (DQCALC) and EPA's Lowes
Authors
William T. Foreman, Teresa Lynne Williams, Edward Furlong, Dawn Hemmerle, Sarah Stetson, Virendra K. Jha, Mary C Noriega, Jessica A Decess, Carmen Reed-Parker, Mark W. Sandstrom
Common insecticide disrupts aquatic communities: A mesocosm-to-field ecological risk assessment of fipronil and its degradates in U.S. streams
Insecticides in streams are increasingly a global concern, yet information on safe concentrations for aquatic ecosystems is sparse. In a 30-day mesocosm experiment exposing native benthic aquatic invertebrates to the common insecticide fipronil and four degradates, fipronil compounds caused altered emergence and trophic cascades. Effect concentrations eliciting a 50% response (EC50) were developed
Authors
Janet L. Miller, Travis S. Schmidt, Peter C. Van Metre, Barbara Mahler, Mark W. Sandstrom, Lisa H. Nowell, Daren Carlisle, Patrick W. Moran
Pesticides and their degradates in groundwater reflect past use and current management strategies, Long Island, New York, USA
Long Island, New York, has a mix of urban/suburban to agricultural/horticultural land use and nearly 3 million residents that rely on a sole-source aquifer for drinking water. The analysis of shallow groundwater (
Authors
Irene Fisher, Patrick J. Phillips, Banu Bayraktar, Shirley Chen, Brendan A. McCarthy, Mark W. Sandstrom
Quality of pesticide data for groundwater analyzed for the National Water-Quality Assessment Project, 2013–18
The National Water-Quality Assessment (NAWQA) Project of the U.S. Geological Survey (USGS) submitted nearly 1,900 samples collected from groundwater sites across the United States in 2013–18 for analysis of 225 pesticide compounds (pesticides and pesticide degradates, hereafter referred to as “pesticides”) by USGS National Water Quality Laboratory schedule 2437 (S2437). For the associated NAWQA st
Authors
Laura M. Bexfield, Kenneth Belitz, Mark W. Sandstrom, Delicia Beaty, Laura Medalie, Bruce D. Lindsey, Lisa H. Nowell
Daily stream samples reveal highly complex pesticide occurrence and potential toxicity to aquatic life
Transient, acutely toxic concentrations of pesticides in streams can go undetected by fixed-interval sampling programs. Here we compare temporal patterns in occurrence of current-use pesticides in daily composite samples to those in weekly composite and weekly discrete samples of surface water from 14 small stream sites. Samples were collected over 10–14 weeks at 7 stream sites in each of the Midw
Authors
Julia E. Norman, Barbara Mahler, Lisa H. Nowell, Peter C. Van Metre, Mark W. Sandstrom, Mark A. Corbin, Yaorong Qian, James F. Pankow, Wentai Luo, Nicholas B. Fitzgerald, William E. Asher, Kevin J. McWhirter
Use of set blanks in reporting pesticide results at the U.S. Geological Survey National Water Quality Laboratory, 2001-15
Executive SummaryBackground.—Pesticide results from the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) are used for water-quality assessments by many agencies and organizations. The USGS is committed to providing data of the highest possible quality to the consumers of its data. A cooperator’s inquiries about specific pesticide detections in water revealed potential laborat
Authors
Laura Medalie, Mark W. Sandstrom, Patricia L. Toccalino, William T. Foreman, Rhiannon C. ReVello, Laura M. Bexfield, Melissa L. Riskin
Data analysis considerations for pesticides determined by National Water Quality Laboratory schedule 2437
In 2013, the U.S. Geological Survey National Water Quality Laboratory (NWQL) made a new method available for the analysis of pesticides in filtered water samples: laboratory schedule 2437. Schedule 2437 is an improvement on previous analytical methods because it determines the concentrations of 225 fungicides, herbicides, insecticides, and associated degradates in one method at similar or lower co
Authors
Megan E. Shoda, Lisa H. Nowell, Wesley W. Stone, Mark W. Sandstrom, Laura M. Bexfield
Complex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams
Aquatic organisms in streams are exposed to pesticide mixtures that vary in composition over time in response to changes in flow conditions, pesticide inputs to the stream, and pesticide fate and degradation within the stream. To characterize mixtures of dissolved-phase pesticides and degradates in Midwestern streams, a synoptic study was conducted at 100 streams during May–August 2013. In weekly
Authors
Lisa H. Nowell, Patrick W. Moran, Travis S. Schmidt, Julia E. Norman, Naomi Nakagaki, Megan E. Shoda, Barbara Mahler, Peter C. Van Metre, Wesley W. Stone, Mark W. Sandstrom, Michelle L. Hladik
Science and Products
- Data
Data for volatile organic compounds in groundwater used for public supply across the United States, 2013-19, and data for associated quality-control samples
This data release includes tables and time-series plots of results for volatile organic compounds (VOCs) analyzed in samples of groundwater used for public supply that were collected by the USGS National Water-Quality Assessment (NAWQA) Project and the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) during 201Data set for a mesocosm to field assessment of the ecological risks associated with neonicotinoids in US streams
Neonicotinoids, a widely used class of insecticide, have been found in surface waters globally. They pose a risk to non-target species found in aquatic environments such as aquatic macroinvertebrates. To better understand the effects of the neonicotinoids imidacloprid, clothianidin and their mixtures on aquatic communities we ran a 30 day mesocosm test. Rock trays were colonized with natural benthData set for an ecological risk assessment of Firpronil compounds in US streams
The phenylpyrazole insecticide fipronil and its degradates are a potential surface-water contaminant and toxicant to nontarget species such as aquatic macroinvertebrates. To better understand how fipronil, fipronil sulfide, fipronil sulfone, desulfinyl fipronil, and fipronil amide affect aquatic communities, a 30-day mesocosm experiment was run. Rock trays were colonized with natural benthic commuDissolved Pesticides in Weekly Water Samples from the NAWQA Regional Stream Quality Assessments (2013-2017)
Dissolved pesticides were measured in weekly water samples from 482 wadeable streams in five regions of the United States during 2013-2017, as part of the U.S. Geological Survey's (USGS) Regional Stream Quality Assessment (RSQA). One study was conducted each year, starting with the Midwest (2013), followed by the Southeast Piedmont (2014), Pacific Northwest (2015), Northeast (2016), and Central CaField, laboratory, and third-party data for assessment of the quality of pesticide results reported by the National Water Quality Laboratory for groundwater samples collected by the National Water-Quality Assessment Project, 2013-18
This data release includes tables and plots of results for pesticide compounds (pesticides and degradates) analyzed in groundwater samples collected by the USGS National Water-Quality Assessment Project during water years 2013-18 and in associated quality-control samples that are used to assess the quality of the reported pesticide results. All samples were analyzed by the USGS National Water QualSupporting Data: Complex Mixtures of Pesticides in Midwest U.S. Streams Indicated by POCIS Time-Integrating Samplers
The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest fo - Multimedia
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Filter Total Items: 53
Ecological consequences of neonicotinoid mixtures in streams
Neonicotinoid mixtures are common in streams worldwide, but corresponding ecological responses are poorly understood. We combined experimental and observational studies to narrow this knowledge gap. The mesocosm experiment determined that concentrations of the neonicotinoids imidacloprid and clothianidin (range of exposures, 0 to 11.9 μg/liter) above the hazard concentration for 5% of species (0.0AuthorsTravis S. Schmidt, Janet L. Miller, Barbara Mahler, Peter C. Van Metre, Lisa H. Nowell, Mark W. Sandstrom, Daren Carlisle, Patrick W. Moran, Paul BradleyFood, beverage, and feedstock processing facility wastewater: A unique and underappreciated source of contaminants to U.S. streams
Process wastewaters from food, beverage, and feedstock facilities, although regulated, are an under-investigated environmental contaminant source. Food process wastewaters (FPWWs) from 23 facilities in 17 U.S. states were sampled and documented for a plethora of chemical and microbial contaminants. Of the 576 analyzed organics, 184 (32%) were detected at least once, with concentrations as large asAuthorsLaura E. Hubbard, Dana W. Kolpin, Carrie E Givens, Bradley D. Blackwell, Paul Bradley, James L. Gray, Rachael F. Lane, Jason R. Masoner, R. Blaine McCleskey, Kristin Romanok, Mark W. Sandstrom, Kelly Smalling, Daniel L. VilleneuveByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, Central Midwest Water Science Center, Kansas Water Science Center, New Jersey Water Science Center, Pennsylvania Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, National Water Quality LaboratoryNew-generation pesticides are prevalent in California's Central Coast streams
Pesticides are widely recognized as important biological stressors in streams, especially in heavily developed urban and agricultural areas like the Central California Coast region. We assessed occurrence and potential toxicity of pesticides in small streams in the region using two analytical methods: a broad-spectrum (223 compounds) method in use since 2012 and a newly developed method for 30 addAuthorsMark W. Sandstrom, Lisa H. Nowell, Barbara Mahler, Peter C. Van MetreInclusion of pesticide transformation products is key to estimating pesticide exposures and effects in small U.S. streams
Improved analytical methods can quantify hundreds of pesticide transformation products (TPs), but understanding of TP occurrence and potential toxicity in aquatic ecosystems remains limited. We quantified 108 parent pesticides and 116 TPs in more than 3 700 samples from 442 small streams in mostly urban basins across five major regions of the United States. TPs were detected nearly as frequently aAuthorsBarbara Mahler, Lisa H. Nowell, Mark W. Sandstrom, Paul Bradley, Kristin Romanok, Christopher Konrad, Peter Van MetreByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, New Jersey Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Washington Water Science Center, National Water Quality LaboratoryComparison of detection limits estimated using single- and multi-concentration spike-based and blank-based procedures
Spike- and blank-based procedures were applied to estimate the detection limits (DLs) for example analytes from inorganic and organic methods for water samples to compare with the U.S. Environmental Protection Agency's (EPA) Method Detection Limit (MDL) procedures (revisions 1.11 and 2.0). The multi-concentration spike-based procedures ASTM Within-laboratory Critical Level (DQCALC) and EPA's LowesAuthorsWilliam T. Foreman, Teresa Lynne Williams, Edward Furlong, Dawn Hemmerle, Sarah Stetson, Virendra K. Jha, Mary C Noriega, Jessica A Decess, Carmen Reed-Parker, Mark W. SandstromCommon insecticide disrupts aquatic communities: A mesocosm-to-field ecological risk assessment of fipronil and its degradates in U.S. streams
Insecticides in streams are increasingly a global concern, yet information on safe concentrations for aquatic ecosystems is sparse. In a 30-day mesocosm experiment exposing native benthic aquatic invertebrates to the common insecticide fipronil and four degradates, fipronil compounds caused altered emergence and trophic cascades. Effect concentrations eliciting a 50% response (EC50) were developedAuthorsJanet L. Miller, Travis S. Schmidt, Peter C. Van Metre, Barbara Mahler, Mark W. Sandstrom, Lisa H. Nowell, Daren Carlisle, Patrick W. MoranPesticides and their degradates in groundwater reflect past use and current management strategies, Long Island, New York, USA
Long Island, New York, has a mix of urban/suburban to agricultural/horticultural land use and nearly 3 million residents that rely on a sole-source aquifer for drinking water. The analysis of shallow groundwater (AuthorsIrene Fisher, Patrick J. Phillips, Banu Bayraktar, Shirley Chen, Brendan A. McCarthy, Mark W. SandstromQuality of pesticide data for groundwater analyzed for the National Water-Quality Assessment Project, 2013–18
The National Water-Quality Assessment (NAWQA) Project of the U.S. Geological Survey (USGS) submitted nearly 1,900 samples collected from groundwater sites across the United States in 2013–18 for analysis of 225 pesticide compounds (pesticides and pesticide degradates, hereafter referred to as “pesticides”) by USGS National Water Quality Laboratory schedule 2437 (S2437). For the associated NAWQA stAuthorsLaura M. Bexfield, Kenneth Belitz, Mark W. Sandstrom, Delicia Beaty, Laura Medalie, Bruce D. Lindsey, Lisa H. NowellDaily stream samples reveal highly complex pesticide occurrence and potential toxicity to aquatic life
Transient, acutely toxic concentrations of pesticides in streams can go undetected by fixed-interval sampling programs. Here we compare temporal patterns in occurrence of current-use pesticides in daily composite samples to those in weekly composite and weekly discrete samples of surface water from 14 small stream sites. Samples were collected over 10–14 weeks at 7 stream sites in each of the MidwAuthorsJulia E. Norman, Barbara Mahler, Lisa H. Nowell, Peter C. Van Metre, Mark W. Sandstrom, Mark A. Corbin, Yaorong Qian, James F. Pankow, Wentai Luo, Nicholas B. Fitzgerald, William E. Asher, Kevin J. McWhirterUse of set blanks in reporting pesticide results at the U.S. Geological Survey National Water Quality Laboratory, 2001-15
Executive SummaryBackground.—Pesticide results from the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) are used for water-quality assessments by many agencies and organizations. The USGS is committed to providing data of the highest possible quality to the consumers of its data. A cooperator’s inquiries about specific pesticide detections in water revealed potential laboratAuthorsLaura Medalie, Mark W. Sandstrom, Patricia L. Toccalino, William T. Foreman, Rhiannon C. ReVello, Laura M. Bexfield, Melissa L. RiskinData analysis considerations for pesticides determined by National Water Quality Laboratory schedule 2437
In 2013, the U.S. Geological Survey National Water Quality Laboratory (NWQL) made a new method available for the analysis of pesticides in filtered water samples: laboratory schedule 2437. Schedule 2437 is an improvement on previous analytical methods because it determines the concentrations of 225 fungicides, herbicides, insecticides, and associated degradates in one method at similar or lower coAuthorsMegan E. Shoda, Lisa H. Nowell, Wesley W. Stone, Mark W. Sandstrom, Laura M. BexfieldComplex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams
Aquatic organisms in streams are exposed to pesticide mixtures that vary in composition over time in response to changes in flow conditions, pesticide inputs to the stream, and pesticide fate and degradation within the stream. To characterize mixtures of dissolved-phase pesticides and degradates in Midwestern streams, a synoptic study was conducted at 100 streams during May–August 2013. In weeklyAuthorsLisa H. Nowell, Patrick W. Moran, Travis S. Schmidt, Julia E. Norman, Naomi Nakagaki, Megan E. Shoda, Barbara Mahler, Peter C. Van Metre, Wesley W. Stone, Mark W. Sandstrom, Michelle L. Hladik