Per- and polyfluoroalkyl substances (PFAS) are a group of anthropogenic emerging contaminants. Some PFAS have been voluntarily phased out, as exposure has been linked to adverse human health effects.
Per- and polyfluoroalkyl substances (PFAS) are a group of emerging contaminants that includes perfluorooctanoic acid (PFOA), perfluorooctanesulfonic acid (PFOS), hexafluoropropylene oxide-dimer acid (more commonly known as GenX®), and many other compounds.
Since the 1940s, PFAS have been manufactured and used around the globe, including in the United States, in a variety of industries such as firefighting foam for flammable liquids. These chemicals are very persistent in the environment, and some PFAS are known to accumulate over time in the human body and in the food chain. Exposure to some PFAS has been linked to adverse human and ecosystem health effects.
PFAS-containing firefighting foams have been widely used at military installations, petroleum refineries, chemical manufacturing plants, civilian airports and fire-training facilities. PFAS are also found in a wide range of consumer products such as cookware, fast-food wrappers and containers, and stain and water repellents, and can lead to human exposure. PFAS are also widely used in a variety of industrial products such as paint, detergents, waxes, and metal plating solution. The most-studied PFAS chemicals are PFOA and PFOS. Studies have linked PFOS and PFOA to numerous health effects including reproductive, developmental, liver, endocrine, and immunological effects. Both chemicals have caused tumors in animals. PFOA, PFOS, perfluorononanoic acid (PFNA), and other PFAS have been found in a number of drinking water systems in the Northeast.
There are numerous large PFAS-contaminated groundwater plumes and impacted surface water bodies throughout the Northeast Atlantic-Appalachian Region (NAAR). Water availability can be impacted by contamination. PFAS contamination in the NAAR has a high likelihood to impact drinking water and human health in these densely populated areas, where water supplies are already stressed.
The scope of PFAS contamination in the US is extensive. USGS development of field methods, assessment of water quality and ecosystem effects, and research findings on PFAS, including fate and transport processes and viable techniques for site remediation, will support federal, state, and local site managers, regulatory agencies, and private remediation firms.
Map ID | Location | Project | Description | Website | Contact |
---|---|---|---|---|---|
1 | North Bennington, VT | Groundwater Age of Private Domestic Wells Contaminated with PFAS in Vermont | Collaboration with the state of Vermont to estimate age distributions of groundwater from private domestic wells containing PFAS. Age tracer models were correlated with PFAS, revealing that wells with larger fractions of younger water generally had higher PFAS concentrations. | Vermont PFOA Contamination | James Shanley, USGS New England WSC, jshanley@usgs.gov; Joseph Ayotte, USGS New England WSC, jayotte@usgs.gov |
2 | Joint Base Cape Cod, MA | Joint Base Cape Cod PFAS Fate & Transport | Study explores the persistence and transport of PFAS that originated from both firefighting and domestic wastewater sources in Cape Cod, along with precursors, temporal trends, diverse contaminant mixtures, groundwater discharge ecosystem buffers, sewage effects and fish impacts. | PFAS in Groundwater for Decades | Andrea Tokranov, USGS New England WSC, atokranov@usgs.gov; Denis LeBlanc, USGS New England WSC, dleblanc@usgs.gov; Larry Barber, USGS Water Mission Area, lbbarber@usgs.gov |
3 | Long Island, NY | Long Island, New York- PFAS Occurrence & Distribution | Monitoring PFAS occurrence and distribution in groundwater monitoring wells. 2018 shallow (<100ft) groundwater monitoring study found PFOA & PFOS concentrations are below the EPA health advisory of 70 ng/L for drinking water. The current study includes monitoring wells that are deeper and screened in the drinking water aquifer. | Monitoring of Groundwater on Long Island & Groundwater Quality of Nassau County | Irene Fisher, USGS NY WSC, ifisher@usgs.gov |
4 | Long Island, NY | Suffolk County, Long Island, NY - Fate of PFAS within wastewater treatment plants | This study evaluates the removal efficiency of organic contaminants at select decentralized wastewater treatment plants and quantifies the amount of contamination discharged by the plant to either shallow groundwater or a surface water body. The analysis includes 28 PFAS. | Irene Fisher, USGS NY WSC, ifisher@usgs.gov |
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5 | Bronx River, NYC, NY | Preliminary quantification of PFAS in the Bronx River, NY | Assessment of PFAS, pharmaceuticals, and pesticides in stream water samples during baseflow and stormflow. The data provides local managers baseline data to support continued restoration efforts and to aid in identification of sources for management of PFAS | Urban Waters Federal Partnership Cooperative Matching Funds | Irene Fisher, USGS NY WSC, ifisher@usgs.gov |
6 | Joint Base McGuire-Dix Lakehurst, NJ | PFAS technical assistance at Joint Base McGuire-Dix Lakehurst | A MODLOW6 groundwater flow model is in development to estimate migration pathways of PFAS within groundwater at JBMDL. In addition, a gain/loss study is evaluating the potential for PFAS found in two lakes near JBMDL to flow out of the surface water and enter the underlying aquifer that supplies drinking water to the area. New Jersey Water Science Center studies in cooperation with the Air Force Civil Engineer Center. | Joint Base MDL Base-wide PFAS Assessment | Alex Fiore, USGS NJ WSC, afiore@usgs.gov |
7 | West Trenton, NJ | Naval Air Force Warfare Center (NAWC) Trenton PFAS assessments | The New Jersey Water Science Center provides technical assistance to the U.S. Navy at the NAWC site regarding PFAS contamination associated with aqueous film forming foam (AFFF) use in the 1980s. Since 2015, the occurrence and distribution of PFAS has been monitored and assessed. PFOS concentrations as high as 26,000 nanograms per liter (ng/L) and PFOA concentrations as high as 2,000 ng/L have been found in groundwater. | Contaminant Fate & Transport at NAWC, NJ | Alex Fiore, USGS NJ WSC, afiore@usgs.gov |
8 | Delaware River Basin, New Jersey | PFAS Passive Sampler Evaluation in New Jersey Groundwater | An evaluation of passive sampling methods for PFAS is being conducted using regenerated cellulose dialysis membrane (RCDM) and commercially available EON Dual Membrane® (DM) passive samplers that were deployed concurrently in 27 long-term monitoring wells throughout the Delaware River Basin in New Jersey and at 2 wells at Naval Air Warfare Center base in Trenton, NJ, in cooperation with USGS Next Generation Water Observing System Delaware River Basin. Samples are collected by conventional purge methods upon retrieval of the passive samplers in cooperation with NJ Ambient Surface Water Quality Monitoring Network for analysis of PFAS as well as nutrients, major ions, pesticides, VOCs, filtered trace elements, DOC, gross alpha and beta radioactivity. | Passive Sampling of Groundwater Wells for Determination of Water Chemistry | Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov |
- | State of New Jersey | New Jersey Ambient Surface-Water-Quality Network | New Jersey Water Science Center, in cooperation with NJ Department of Environmental Protection, is collecting discrete surface-water samples of PFAS as part of the NJ Ambient Surface Water Quality Monitoring Network, as a synoptic of 123 sites twice per year targeting baseflow and elevated streamflow conditions. Laboratory analysis includes 28 PFAS compounds. | New Jersey Ambient Surface-Water-Quality Monitoring Network | Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov; Anna Boetsma, USGS NJ WSC, aboetsma@usgs.gov |
- | State of New Jersey | New Jersey Ambient Groundwater Quality Monitoring Network | New Jersey Water Science Center, in cooperation with NJ Department of Environmental Protection, annually collects groundwater samples for PFAS and nutrients, major ions, pesticides, VOCs, filtered trace elements, DOC, gross alpha and beta radioactivity by conventional-purge methods at 50 long-term monitoring wells as part of the cooperative NJ Ambient Groundwater Quality Monitoring Network. | New Jersey Ambient Groundwater-Quality Monitoring Network | Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov; Anna Boetsma, USGS NJ WSC, aboetsma@usgs.gov |
9 | Willow Grove and Warminster, PA | Regional Flow Paths of PFAS-Contaminated Groundwater at Willow Grove and Warminster, Pennsylvania | PFAS detected in wells near Willow Grove and Warminster Bases in 2014, leading to shutdown of 5 public supply wells and additional wells later. This study will improve the understanding of groundwater flow rates and directions by developing a preliminary numerical groundwater-flow model and help identify data gaps and selection of additional monitoring locations. | Contaminants in Groundwater near former PA Navy Bases | Joe Duris, USGS PA WSC, jwduris@usgs.gov; Lisa Senior, USGS PA WSC, lasenior@usgs.gov |
- | State of Pennsylvania | Pennsylvania Water Science Center (PA WSC) - Measurement of PFAS in Surface Waters | The Pennsylvania Water Science Center is working with the Pennsylvania Department of Environmental Protection and experts across the Nation to develop and implement rigorous and innovative techniques to detect PFAS at concentrations as low as parts per trillion to help the public understand the spatial distribution and magnitude of PFAS contamination within the environment. | Hydrologic and Water Quality Studies of PFAS in Pennsylvania & Survey of PFAS in PA Surface Waters
|
Joe Duris, USGS PA WSC, jwduris@usgs.gov |
10 | (A) Joint Base Andrews, MD & (B) Willow Grove, PA | Effects of PFAS Exposure in Tree Swallows | The Upper Midwest Environmental Sciences Center (UMESC) and Patuxent Wildlife Research Center (PWRC) are examining both exposure to and possible effects such as immune and health effects of PFAS in tree swallows at two Department of Defense sites (Joint Base Andrews & Willow Grove), with Patuxent Research Refuge as a background site. | Immune System Changes in Birds Exposed to Environmental Contaminants | Christine Custer, UMESC, ccuster@usgs.gov; Natalie Karouna-Renier, PWRC, nkarouna@usgs.gov |
11 | Antietam Creek, MD | PFAS Exposure and Effects in Smallmouth Bass | Smallmouth bass in Antietam Creek, MD were found to have high levels of PFAS. Further studies on immune health of PFAS-exposed smallmouth bass are being conducted. | Forever Chemicals Found in Chesapeake Fish | Vicki Blazer, USGS Leetown SC, vblazer@usgs.gov |
12 | Baltimore, MD | PFAS Biotransformation and Effect of Chlorinated Organic Co-Contaminants | Investigation of natural and enhanced biotransformation of PFAS and co-contaminants and associated changes in microbial communities. Experiments utilize sediment samples from areas of groundwater discharge to streams at multiple contaminated sites and comparisons with an established dechlorinating culture. Conducted under the Environmental Health Program, Ecosystems. | Michelle M. Lorah, MD/DE/DC WSC, mmlorah@usgs.gov; Denise Akob, USGS Geology, Energy & Minerals SC, dakob@usgs.gov |
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12 | Baltimore, MD | PFAS Fate and Transport Processes in a Physical Aquifer Model | Testing with a one-fifth scale physical aquifer model to evaluate sorption and transport of PFAS under continuous and pulse sources. SERDP Limited Scope project, led by US Army Corps of Engineers Baltimore District, in collaboration with USGS MD-DE-DC Water Science Center and University of Maryland Baltimore County. | Ethan Weikel, USGS MD/DE/DC WSC, weikel@usgs.gov |
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13 | Chesapeake Bay, MD | PFAS in Maryland Stormwater Controls | PFAS analysis in wet pond sediment as part of a USGS Chesapeake Bay Studies project in collaboration with Maryland Department of Environment. Sediment will be analyzed from over 60 wet ponds across different land uses (old residential, new residential, commercial, industrial) across Maryland. | Emily Majcher, USGS MD/DE/DC WSC, emajcher@usgs.gov |
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- | Delaware | PFAS in Delaware Drinking Water | Source water assessment of Delaware public water supplies that included sampling 30 wells for PFAS. | Batzaida Reyes, USGS MD/DE/DC WSC, breyes@usgs.gov |
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14 | Shenandoah River, VA | Accumulated Wastewater Ratio (ACCWW) Modeling | Refinement of the existing national-scale “de facto reuse incidence in our nation’s consumable supply” (DRINCS) model, complemented by field measurements, provides a screening tool to understand human and wildlife exposure to toxicants, including PFAS, and pathogens associated with the incidental reuse of treated wastewater in the Shenandoah River watershed. | Understanding Exposure to Contaminants from Wastewater Reuse | Larry Barber, USGS Water Mission Area, lbbarber@usgs.gov Jennifer Rapp, USGS V/WV WSC, jrapp@usgs.gov |
- | State of West Virginia | PFAS in the State of West Virgina | The Virginia and West Virginia Water Science Center is working with the state of West Virginia to identify PFAS contamination in West Virginia's public source water supplies. | Mitch McAdoo, USGS V/WV WSC, mmcadoo@usgs.gov |
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- | Great Lakes Basin | Great Lake Restoration: Toxic Substances and Areas of Concern | Selected tributaries of the Great Lakes Basin collected sediment and water samples using Polar Organic Chemical Integrative Samplers (POCIS) passive samplers including a few selected streams draining Department of Defense (DOD) facilities and airports. | Toxic Substances in Great Lakes & POCIS Samplers | Steve Corsi, USGS Upper Midwest WSC, srcorsi@usgs.gov |
- | Western Ohio | Wright-Patterson Air Force Base Monitoring (western Ohio) | Project includes surface water sampling and measuring ground water vectors using horizontal flow-meters. Funded by Air Force Civil Engineering Center (AFCEC). | Randall Bayless, USGS OH/KY/IN WSC, ebayless@usgs.gov |
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- | National- United States | Environmental Health Program, Ecosystems, National Tap Water Project | Study to provide information on contaminant exposure from tap water at 26 locations including public and private supplies. Public-supply tap water generally met enforceable standards for those compounds with standards. Samples consisted of contaminant mixtures that are not commonly monitored and for which the health risks are unknown, including PFAS. | Pilot Study Provides Information on Contaminant Exposure from Tap Water in the US | Paul Bradley, USGS South Atlantic WSC, pbradley@usgs.gov; Kelly Smalling, USGS NJ WSC, ksmall@usgs.gov |
- | National- United States | PFAS detected in Source Waters and Treated Public Water Supplies | This study, which measured 17 per- and polyfuoroalkyl substances (PFASs) in source and treated public water supplies from 25 drinking water facilities as part of a broader study of contaminants in drinking water across the United States, reports that PFASs were detected in all source water and public water supply samples collected. One sample exceeded the current U.S. Environmental Protection Agency (EPA) drinking water health advisory that applies to two of the compounds measured. | PFAS in Sorce and Treated Public Water | Ed Furlong, USGS Water Mission Area, efurlong@usgs.gov |
USGS science projects associated with current PFAS studies:
Hydrologic and Water Quality Studies of PFAS in Pennsylvania
Investigations and Technical Assistance to the Joint Base McGuire-Dix-Lakehurst, New Jersey, in Assessing the Distribution and Transport of Perfluorinated Compounds in Groundwater and Surface Water
No Adverse Reproductive Effects Observed in Tree Swallows Exposed to Perfluoroalkyl Substances in Clarks Marsh, Michigan
Per- and Polyfluoroalkyl Substances (PFASs) detected in Source Waters and Treated Public Water Supplies
Per- and Polyfluoroalkyl Substances From Firefighting and Domestic Wastewater Remain in Groundwater for Decades
USGS data or web applications associated with PFAS studies:
Per-and Polyfluorinated Alkyl Substances (PFAS) and associated ancillary data from the Commonwealth of Pennsylvania, USA, 2019
Assessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
Mixed Organic and Inorganic Tapwater Results in the Greater Chicago Area, USA, 2017-2019
Publications associated with USGS PFAS studies:
Mixed organic and inorganic tapwater exposures and potential effects in greater Chicago area, USA
Groundwater withdrawals and regional flow paths at and near Willow Grove and Warminster, Pennsylvania—Data compilation and preliminary simulations for conditions in 1999, 2010, 2013, 2016, and 2017
Urban stormwater: An overlooked pathway of extensive mixed contaminants to surface and groundwaters in the United States
Perfluoroalkyl contaminant exposure in tree swallows nesting at Clarks Marsh, Oscoda, Michigan, USA
Per- and polyfluoroalkyl substances (PFAS) in plasma of the West Indian manatee (Trichechus manatus)
Reconnaissance of mixed organic and inorganic chemicals in private and public supply tapwaters at selected residential and workplace sites in the United States
Safe drinking water at the point-of-use (tapwater, TW) is a United States public health priority. Multiple lines of evidence were used to evaluate potential human health concerns of 482 organics and 19 inorganics in TW from 13 (7 public supply, 6 private well self-supply) home and 12 (public supply) workplace locations in 11 states. Only uranium (61.9 μg L–1, private well) exceeded a National Prim
Methods used for the collection and analysis of chemical and biological data for the Tapwater Exposure Study, United States, 2016–17
Concentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017
EROD activity, chromosomal damage, and oxidative stress in response to contaminants exposure in tree swallow (Tachycineta bicolor) nestlings from Great Lakes Areas of Concern
Geochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
Contaminants of emerging concern in the Great Lakes Basin: A report on sediment, water, and fish tissue chemistry collected in 2010-2012
Organic contamination in tree swallow (Tachycineta bicolor) nestlings at United States and binational great Lakes Areas of Concern
News stories associated with USGS PFAS studies:
- Overview
Per- and polyfluoroalkyl substances (PFAS) are a group of anthropogenic emerging contaminants. Some PFAS have been voluntarily phased out, as exposure has been linked to adverse human health effects.
Per- and polyfluoroalkyl substances (PFAS) are a group of emerging contaminants that includes perfluorooctanoic acid (PFOA), perfluorooctanesulfonic acid (PFOS), hexafluoropropylene oxide-dimer acid (more commonly known as GenX®), and many other compounds.
USGS Hydrologic Technician assisting with the collection of soil and worm samples in an area on Cape Cod impacted by PFAS contamination. Since the 1940s, PFAS have been manufactured and used around the globe, including in the United States, in a variety of industries such as firefighting foam for flammable liquids. These chemicals are very persistent in the environment, and some PFAS are known to accumulate over time in the human body and in the food chain. Exposure to some PFAS has been linked to adverse human and ecosystem health effects.
PFAS-containing firefighting foams have been widely used at military installations, petroleum refineries, chemical manufacturing plants, civilian airports and fire-training facilities. PFAS are also found in a wide range of consumer products such as cookware, fast-food wrappers and containers, and stain and water repellents, and can lead to human exposure. PFAS are also widely used in a variety of industrial products such as paint, detergents, waxes, and metal plating solution. The most-studied PFAS chemicals are PFOA and PFOS. Studies have linked PFOS and PFOA to numerous health effects including reproductive, developmental, liver, endocrine, and immunological effects. Both chemicals have caused tumors in animals. PFOA, PFOS, perfluorononanoic acid (PFNA), and other PFAS have been found in a number of drinking water systems in the Northeast.
USGS scientist preparing a PFAS biodegradation microcosm to mimic a simplified ecosystem in the Fate and Bioremediation Laboratory at the MD-DE-DC Water Science Center.(Credit: Michelle Lorah, US Geological Survey. Public domain.) There are numerous large PFAS-contaminated groundwater plumes and impacted surface water bodies throughout the Northeast Atlantic-Appalachian Region (NAAR). Water availability can be impacted by contamination. PFAS contamination in the NAAR has a high likelihood to impact drinking water and human health in these densely populated areas, where water supplies are already stressed.
The scope of PFAS contamination in the US is extensive. USGS development of field methods, assessment of water quality and ecosystem effects, and research findings on PFAS, including fate and transport processes and viable techniques for site remediation, will support federal, state, and local site managers, regulatory agencies, and private remediation firms.
NAAR Regional Map of PFAS Projects listed with Map IDs. Map ID Location Project Description Website Contact 1 North Bennington, VT Groundwater Age of Private Domestic Wells Contaminated with PFAS in Vermont Collaboration with the state of Vermont to estimate age distributions of groundwater from private domestic wells containing PFAS. Age tracer models were correlated with PFAS, revealing that wells with larger fractions of younger water generally had higher PFAS concentrations. Vermont PFOA Contamination James Shanley,
USGS New England WSC, jshanley@usgs.gov;
Joseph Ayotte,
USGS New England WSC, jayotte@usgs.gov2 Joint Base Cape Cod, MA Joint Base Cape Cod PFAS Fate & Transport Study explores the persistence and transport of PFAS that originated from both firefighting and domestic wastewater sources in Cape Cod, along with precursors, temporal trends, diverse contaminant mixtures, groundwater discharge ecosystem buffers, sewage effects and fish impacts. PFAS in Groundwater for Decades Andrea Tokranov, USGS New England WSC, atokranov@usgs.gov; Denis LeBlanc,
USGS New England WSC, dleblanc@usgs.gov; Larry Barber, USGS Water Mission Area, lbbarber@usgs.gov3 Long Island, NY Long Island, New York- PFAS Occurrence & Distribution Monitoring PFAS occurrence and distribution in groundwater monitoring wells. 2018 shallow (<100ft) groundwater monitoring study found PFOA & PFOS concentrations are below the EPA health advisory of 70 ng/L for drinking water. The current study includes monitoring wells that are deeper and screened in the drinking water aquifer. Monitoring of Groundwater on Long Island & Groundwater Quality of Nassau County Irene Fisher,
USGS NY WSC,
ifisher@usgs.gov4 Long Island, NY Suffolk County, Long Island, NY - Fate of PFAS within wastewater treatment plants This study evaluates the removal efficiency of organic contaminants at select decentralized wastewater treatment plants and quantifies the amount of contamination discharged by the plant to either shallow groundwater or a surface water body. The analysis includes 28 PFAS. Irene Fisher,
USGS NY WSC, ifisher@usgs.gov5 Bronx River, NYC, NY Preliminary quantification of PFAS in the Bronx River, NY Assessment of PFAS, pharmaceuticals, and pesticides in stream water samples during baseflow and stormflow. The data provides local managers baseline data to support continued restoration efforts and to aid in identification of sources for management of PFAS Urban Waters Federal Partnership Cooperative Matching Funds Irene Fisher,
USGS NY WSC, ifisher@usgs.gov6 Joint Base McGuire-Dix Lakehurst, NJ PFAS technical assistance at Joint Base McGuire-Dix Lakehurst A MODLOW6 groundwater flow model is in development to estimate migration pathways of PFAS within groundwater at JBMDL. In addition, a gain/loss study is evaluating the potential for PFAS found in two lakes near JBMDL to flow out of the surface water and enter the underlying aquifer that supplies drinking water to the area. New Jersey Water Science Center studies in cooperation with the Air Force Civil Engineer Center. Joint Base MDL Base-wide PFAS Assessment Alex Fiore,
USGS NJ WSC,
afiore@usgs.gov7 West Trenton, NJ Naval Air Force Warfare Center (NAWC) Trenton PFAS assessments The New Jersey Water Science Center provides technical assistance to the U.S. Navy at the NAWC site regarding PFAS contamination associated with aqueous film forming foam (AFFF) use in the 1980s. Since 2015, the occurrence and distribution of PFAS has been monitored and assessed. PFOS concentrations as high as 26,000 nanograms per liter (ng/L) and PFOA concentrations as high as 2,000 ng/L have been found in groundwater. Contaminant Fate & Transport at NAWC, NJ Alex Fiore,
USGS NJ WSC, afiore@usgs.gov8 Delaware River Basin, New Jersey PFAS Passive Sampler Evaluation in New Jersey Groundwater An evaluation of passive sampling methods for PFAS is being conducted using regenerated cellulose dialysis membrane (RCDM) and commercially available EON Dual Membrane® (DM) passive samplers that were deployed concurrently in 27 long-term monitoring wells throughout the Delaware River Basin in New Jersey and at 2 wells at Naval Air Warfare Center base in Trenton, NJ, in cooperation with USGS Next Generation Water Observing System Delaware River Basin. Samples are collected by conventional purge methods upon retrieval of the passive samplers in cooperation with NJ Ambient Surface Water Quality Monitoring Network for analysis of PFAS as well as nutrients, major ions, pesticides, VOCs, filtered trace elements, DOC, gross alpha and beta radioactivity. Passive Sampling of Groundwater Wells for Determination of Water Chemistry Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov - State of New Jersey New Jersey Ambient Surface-Water-Quality Network New Jersey Water Science Center, in cooperation with NJ Department of Environmental Protection, is collecting discrete surface-water samples of PFAS as part of the NJ Ambient Surface Water Quality Monitoring Network, as a synoptic of 123 sites twice per year targeting baseflow and elevated streamflow conditions. Laboratory analysis includes 28 PFAS compounds. New Jersey Ambient Surface-Water-Quality Monitoring Network Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov;
Anna Boetsma,
USGS NJ WSC,
aboetsma@usgs.gov- State of New Jersey New Jersey Ambient Groundwater Quality Monitoring Network New Jersey Water Science Center, in cooperation with NJ Department of Environmental Protection, annually collects groundwater samples for PFAS and nutrients, major ions, pesticides, VOCs, filtered trace elements, DOC, gross alpha and beta radioactivity by conventional-purge methods at 50 long-term monitoring wells as part of the cooperative NJ Ambient Groundwater Quality Monitoring Network. New Jersey Ambient Groundwater-Quality Monitoring Network Heather Heckathorn, USGS NJ WSC, haheck@usgs.gov; Anna Boetsma, USGS NJ WSC, aboetsma@usgs.gov 9 Willow Grove and Warminster, PA Regional Flow Paths of PFAS-Contaminated Groundwater at Willow Grove and Warminster, Pennsylvania PFAS detected in wells near Willow Grove and Warminster Bases in 2014, leading to shutdown of 5 public supply wells and additional wells later. This study will improve the understanding of groundwater flow rates and directions by developing a preliminary numerical groundwater-flow model and help identify data gaps and selection of additional monitoring locations. Contaminants in Groundwater near former PA Navy Bases Joe Duris,
USGS PA WSC, jwduris@usgs.gov; Lisa Senior,
USGS PA WSC, lasenior@usgs.gov- State of Pennsylvania Pennsylvania Water Science Center (PA WSC) - Measurement of PFAS in Surface Waters The Pennsylvania Water Science Center is working with the Pennsylvania Department of Environmental Protection and experts across the Nation to develop and implement rigorous and innovative techniques to detect PFAS at concentrations as low as parts per trillion to help the public understand the spatial distribution and magnitude of PFAS contamination within the environment. Hydrologic and Water Quality Studies of PFAS in Pennsylvania &
Survey of PFAS in PA Surface WatersJoe Duris,
USGS PA WSC, jwduris@usgs.gov10 (A) Joint Base Andrews, MD & (B) Willow Grove, PA Effects of PFAS Exposure in Tree Swallows The Upper Midwest Environmental Sciences Center (UMESC) and Patuxent Wildlife Research Center (PWRC) are examining both exposure to and possible effects such as immune and health effects of PFAS in tree swallows at two Department of Defense sites (Joint Base Andrews & Willow Grove), with Patuxent Research Refuge as a background site. Immune System Changes in Birds Exposed to Environmental Contaminants Christine Custer, UMESC, ccuster@usgs.gov; Natalie Karouna-Renier,
PWRC, nkarouna@usgs.gov11 Antietam Creek, MD PFAS Exposure and Effects in Smallmouth Bass Smallmouth bass in Antietam Creek, MD were found to have high levels of PFAS. Further studies on immune health of PFAS-exposed smallmouth bass are being conducted. Forever Chemicals Found in Chesapeake Fish Vicki Blazer, USGS Leetown SC, vblazer@usgs.gov 12 Baltimore, MD PFAS Biotransformation and Effect of Chlorinated Organic Co-Contaminants Investigation of natural and enhanced biotransformation of PFAS and co-contaminants and associated changes in microbial communities. Experiments utilize sediment samples from areas of groundwater discharge to streams at multiple contaminated sites and comparisons with an established dechlorinating culture. Conducted under the Environmental Health Program, Ecosystems. Michelle M. Lorah, MD/DE/DC WSC,
mmlorah@usgs.gov;
Denise Akob,
USGS Geology, Energy & Minerals SC,
dakob@usgs.gov12 Baltimore, MD PFAS Fate and Transport Processes in a Physical Aquifer Model Testing with a one-fifth scale physical aquifer model to evaluate sorption and transport of PFAS under continuous and pulse sources. SERDP Limited Scope project, led by US Army Corps of Engineers Baltimore District, in collaboration with USGS MD-DE-DC Water Science Center and University of Maryland Baltimore County. Ethan Weikel,
USGS MD/DE/DC WSC, weikel@usgs.gov13 Chesapeake Bay, MD PFAS in Maryland Stormwater Controls PFAS analysis in wet pond sediment as part of a USGS Chesapeake Bay Studies project in collaboration with Maryland Department of Environment. Sediment will be analyzed from over 60 wet ponds across different land uses (old residential, new residential, commercial, industrial) across Maryland. Emily Majcher,
USGS MD/DE/DC WSC, emajcher@usgs.gov- Delaware PFAS in Delaware Drinking Water Source water assessment of Delaware public water supplies that included sampling 30 wells for PFAS. Batzaida Reyes,
USGS MD/DE/DC WSC, breyes@usgs.gov14 Shenandoah River, VA Accumulated Wastewater Ratio (ACCWW) Modeling Refinement of the existing national-scale “de facto reuse incidence in our nation’s consumable supply” (DRINCS) model, complemented by field measurements, provides a screening tool to understand human and wildlife exposure to toxicants, including PFAS, and pathogens associated with the incidental reuse of treated wastewater in the Shenandoah River watershed. Understanding Exposure to Contaminants from Wastewater Reuse Larry Barber,
USGS Water Mission Area, lbbarber@usgs.gov Jennifer Rapp,
USGS V/WV WSC, jrapp@usgs.gov- State of West Virginia PFAS in the State of West Virgina The Virginia and West Virginia Water Science Center is working with the state of West Virginia to identify PFAS contamination in West Virginia's public source water supplies. Mitch McAdoo,
USGS V/WV WSC, mmcadoo@usgs.gov- Great Lakes Basin Great Lake Restoration: Toxic Substances and Areas of Concern Selected tributaries of the Great Lakes Basin collected sediment and water samples using Polar Organic Chemical Integrative Samplers (POCIS) passive samplers including a few selected streams draining Department of Defense (DOD) facilities and airports. Toxic Substances in Great Lakes & POCIS Samplers Steve Corsi,
USGS Upper Midwest WSC,
srcorsi@usgs.gov- Western Ohio Wright-Patterson Air Force Base Monitoring (western Ohio) Project includes surface water sampling and measuring ground water vectors using horizontal flow-meters. Funded by Air Force Civil Engineering Center (AFCEC). Randall Bayless,
USGS OH/KY/IN WSC, ebayless@usgs.gov- National- United States Environmental Health Program, Ecosystems, National Tap Water Project Study to provide information on contaminant exposure from tap water at 26 locations including public and private supplies. Public-supply tap water generally met enforceable standards for those compounds with standards. Samples consisted of contaminant mixtures that are not commonly monitored and for which the health risks are unknown, including PFAS. Pilot Study Provides Information on Contaminant Exposure from Tap Water in the US Paul Bradley,
USGS South Atlantic WSC, pbradley@usgs.gov; Kelly Smalling,
USGS NJ WSC, ksmall@usgs.gov- National- United States PFAS detected in Source Waters and Treated Public Water Supplies This study, which measured 17 per- and polyfuoroalkyl substances (PFASs) in source and treated public water supplies from 25 drinking water facilities as part of a broader study of contaminants in drinking water across the United States, reports that PFASs were detected in all source water and public water supply samples collected. One sample exceeded the current U.S. Environmental Protection Agency (EPA) drinking water health advisory that applies to two of the compounds measured. PFAS in Sorce and Treated Public Water Ed Furlong,
USGS Water Mission Area,
efurlong@usgs.gov - Science
USGS science projects associated with current PFAS studies:
Hydrologic and Water Quality Studies of PFAS in Pennsylvania
USGS is working with federal, state, and local partners to monitor and evaluate perfluoroalkyl and polyfluoroalkyl substances (PFAS) in Pennsylvania's groundwater and surface waters. A recent study sampled tap water in Pennsylvania (and other states) and detected PFAS chemicals in some samples.Investigations and Technical Assistance to the Joint Base McGuire-Dix-Lakehurst, New Jersey, in Assessing the Distribution and Transport of Perfluorinated Compounds in Groundwater and Surface Water
The USGS New Jersey Water Science Center provides hydrologic technical assistance to the U.S. Air Force Civil Engineer Center at Joint Base McGuire-Dix-Lakehurst (JBMDL) in New Jersey, regarding contamination issues associated with perfluoroalkyl substances (PFAS), such as perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), in groundwater and surface water.No Adverse Reproductive Effects Observed in Tree Swallows Exposed to Perfluoroalkyl Substances in Clarks Marsh, Michigan
Perfluoroalkyl substance (PFAS) concentrations in tree swallows (Tachycineta bicolor) breeding at Clarks Marsh near a decommissioned U.S. Air Force base in Michigan were among the highest concentrations ever documented in birds indicating significant PFAS exposures. In contrast to previous studies where reproductive impairment was documented at lower PFAS exposure, there were no adverse effects on...Per- and Polyfluoroalkyl Substances (PFASs) detected in Source Waters and Treated Public Water Supplies
This study, which measured 17 per- and polyfuoroalkyl substances (PFASs) in source and treated public water supplies from 25 drinking water facilities as part of a broader study of contaminants in drinking water across the United States, reports that PFASs were detected in all source water and public water supply samples collected. One sample exceeded the current U.S. Environmental Protection...Per- and Polyfluoroalkyl Substances From Firefighting and Domestic Wastewater Remain in Groundwater for Decades
New study explores the persistence and transport of poly- and perfluoroalkyl substances (PFASs) that originated from both firefighting and domestic wastewater sources. Although the fire training area and wastewater facility were decommissioned over 20 years ago, both sites continue to be sources of PFASs to groundwater. - Data
USGS data or web applications associated with PFAS studies:
Per-and Polyfluorinated Alkyl Substances (PFAS) and associated ancillary data from the Commonwealth of Pennsylvania, USA, 2019
The USGS Pennsylvania Water Science Center (USGS PAWSC) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) has assembled this data release in support of ongoing USGS and PADEP evaluations related to the occurrence and distribution of Per-and Polyfluorinated Alkyl Substances (PFAS) within Pennsylvania surface water. The data is of four general types: Discrete samAssessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic cMixed Organic and Inorganic Tapwater Results in the Greater Chicago Area, USA, 2017-2019
This data set contains the result for inorganic constituents and organic compounds collected from tapwater locations, as well as water filtration plants, in East Chicago, Indiana, and Chicago, Illinois in 2017. Additionally quality assurance data collected was summarized. Residential samples collected were done so directly from residential kitchen taps (faucets) as is, it was noted if a point-of-u - Publications
Publications associated with USGS PFAS studies:
Filter Total Items: 30Mixed organic and inorganic tapwater exposures and potential effects in greater Chicago area, USA
Safe drinking water at the point of use (tapwater, TW) is a public-health priority. TW exposures and potential human-health concerns of 540 organics and 35 inorganics were assessed in 45 Chicago area United States (US) homes in 2017. No US Environmental Protection Agency (EPA) enforceable Maximum Contaminant Level(s) (MCL) were exceeded in any residential or water treatment plant (WTP) pre-distribAuthorsPaul Bradley, Maria Argos, Dana W. Kolpin, Shannon M. Meppelink, Kristin Romanok, Kelly Smalling, Michael J. Focazio, Joshua M. Allen, Julie E. Dietze, Michael J. Devito, Ariel Donovan, Nicola Evans, Carrie E. Givens, James L. Gray, Christopher P. Higgins, Michelle Hladik, Luke Iwanowicz, Celeste A. Journey, Rachael F. Lane, Zachary Laughrey, Keith A. Loftin, R. Blaine McCleskey, Carrie A. McDonough, Elizabeth K Medlock Kakaley, Michael T. Meyer, Andrea Holthouse-Putz, Susan D Richardson, Alan Stark, Christopher P. Weis, Vickie S. Wilson, Abderrahman ZehraouiGroundwater withdrawals and regional flow paths at and near Willow Grove and Warminster, Pennsylvania—Data compilation and preliminary simulations for conditions in 1999, 2010, 2013, 2016, and 2017
In 2014, groundwater samples from residential and public supply wells in the vicinity of two former U.S. Navy bases at Willow Grove and Warminster, and an active Air National Guard Station at Horsham, Bucks and Montgomery Counties, Pennsylvania, were found to have concentrations of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), which are per- and polyfluoroalkyl substances (PFAuthorsDaniel J. Goode, Lisa A. SeniorUrban stormwater: An overlooked pathway of extensive mixed contaminants to surface and groundwaters in the United States
Increasing global reliance on stormwater control measures to reduce discharge to surface water, increase groundwater recharge, and minimize contaminant delivery to receiving waterbodies necessitates improved understanding of stormwater-contaminant profiles. A multi-agency study of organic and inorganic chemicals in urban stormwater from 50 runoff events at 21 sites across the United States demonstAuthorsJason R. Masoner, Dana W. Kolpin, Isabelle M. Cozzarelli, Larry B. Barber, D.S. Burden, William T. Foreman, Kenneth J. Forshay, Edward Furlong, Justin F. Groves, Michelle Hladik, Matthew E. Hopton, Jeanne B. Jaeschke, Steffanie H. Keefe, David Krabbenhoft, Richard Lowrance, Kristin Romanok, David L. Rus, William R. Selbig, Brad Williams, Paul BradleyByWater Resources Mission Area, Science Synthesis, Analysis and Research Program, Contaminant Biology, Science Analytics and Synthesis (SAS) Program, Toxic Substances Hydrology, California Water Science Center, Central Midwest Water Science Center, New Jersey Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Environmental Sciences Center, Upper Midwest Water Science Center, Reston Biogeochemical Processes in Groundwater LaboratoryPerfluoroalkyl contaminant exposure in tree swallows nesting at Clarks Marsh, Oscoda, Michigan, USA
A site in north eastern Michigan, Oscoda Township, has some of the highest recorded exposure in birds to perfluorinated substances (PFASs) in the U.S. Some egg and plasma concentrations at that location exceeded the lowest reproductive effect threshold established for two avian laboratory species. The objectives of this study were to determine whether there were reproductive effects or physiologAuthorsChristine M. Custer, Thomas W. Custer, Robert Delaney, Paul Dummer, Sandra L. Schultz, Natalie K. Karouna-RenierPer- and polyfluoroalkyl substances (PFAS) in plasma of the West Indian manatee (Trichechus manatus)
Per- and polyfluoroalkyl substances (PFAS) are ubiquitous, synthetic anthropogenic chemicals known to infiltrate and persist in biological systems as a result of their stability and bioaccumulation potential. This study investigated 15 PFAS, including short-chain carboxylic and sulfonic acids, and their presence in a threatened herbivore, the West Indian manatee (Trichechus manatus). Seven of theAuthorsKady Palmer, Jacqueline T. Bangma, Jessica L. Reiner, Robert K. Bonde, Jeffrey E. Korte, Ashley S. P. Boggs, John A. BowdenReconnaissance of mixed organic and inorganic chemicals in private and public supply tapwaters at selected residential and workplace sites in the United States
Safe drinking water at the point-of-use (tapwater, TW) is a United States public health priority. Multiple lines of evidence were used to evaluate potential human health concerns of 482 organics and 19 inorganics in TW from 13 (7 public supply, 6 private well self-supply) home and 12 (public supply) workplace locations in 11 states. Only uranium (61.9 μg L–1, private well) exceeded a National Prim
AuthorsPaul M. Bradley, Dana W. Kolpin, Kristin M. Romanok, Kelly L. Smalling, Michael J. Focazio, Juliane B. Brown, Mary C. Cardon, Kurt D. Carpenter, Steven R. Corsi, Laura A. DeCicco, Julie E. Dietze, Nicola Evans, Edward T. Furlong, Carrie E. Givens, James L. Gray, Dale W. Griffin, Christopher P. Higgins, Michelle L. Hladik, Luke R. Iwanowicz, Celeste A. Journey, Kathryn Kuivila, Jason R. Masoner, Carrie A. McDonough, Michael T. Meyer, James L. Orlando, Mark J. Strynar, Christopher P. Weis, Vickie S. WilsonByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Central Midwest Water Science Center, Colorado Water Science Center, Eastern Ecological Science Center, Kansas Water Science Center, New Jersey Water Science Center, Oregon Water Science Center, South Atlantic Water Science Center (SAWSC), St. Petersburg Coastal and Marine Science Center, Upper Midwest Environmental Sciences Center, Upper Midwest Water Science Center, National Water Quality LaboratoryMethods used for the collection and analysis of chemical and biological data for the Tapwater Exposure Study, United States, 2016–17
In 2016, the U.S. Geological Survey (USGS) Environmental Health Mission Area, initiated the Tapwater Exposure Study as part of an infrastructure project to assess human exposure to potential threats from complex mixtures of contaminants. In the pilot phase (2016), samples were collected from 11 States throughout the United States, and in the second phase (2017), the study focused on the Greater ChAuthorsKristin M. Romanok, Dana W. Kolpin, Shannon M. Meppelink, Maria Argos, Juliane B. Brown, Michael J. Devito, Julie E. Dietze, Carrie E. Givens, James L. Gray, Christopher P. Higgins, Michelle L. Hladik, Luke R. Iwanowicz, Keith A. Loftin, R. Blaine McCleskey, Carrie A. McDonough, Michael T. Meyer, Mark J. Strynar, Christopher P. Weis, Vickie S. Wilson, Paul M. BradleyConcentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017
The U.S. Geological Survey (USGS) Environmental Health Mission Area (EHMA) is providing comprehensive science on sources, movement, and transformation of contaminants and pathogens in watershed and aquifer drinking-water supplies and in built water and wastewater infrastructure (referred to as the USGS Water and Wastewater Infrastructure project) in the Greater Chicago Area and elsewhere in the UnAuthorsKristin M. Romanok, Dana W. Kolpin, Shannon M. Meppelink, Michael J. Focazio, Maria Argos, Mary E. Hollingsworth, R. Blaine McCleskey, Andrea R. Putz, Alan Stark, Christopher P. Weis, Abderrahman Zehraoui, Paul M. BradleyEROD activity, chromosomal damage, and oxidative stress in response to contaminants exposure in tree swallow (Tachycineta bicolor) nestlings from Great Lakes Areas of Concern
Tree swallow, Tachycineta bicolor, nestlings were collected from 60 sites in the Great Lakes, which included multiple sites within 27 Areas of Concern (AOCs) and six sites not listed as AOCs from 2010 to 2014. Nestlings, approximately 12 days-of-age, were evaluated for ethoxyresorufin-O-dealkylase (EROD) activity, chromosomal damage, and six measures of oxidative stress. Data on each of these biomAuthorsThomas W. Custer, Christine M. Custer, Paul Dummer, Emilie Bigorgne, Elias Oziolor, Natalie K. Karouna-Renier, Sandra L. Schultz, Richard A. Erickson, Kevin Aagaard, Cole W. MatsonGeochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
AuthorsAndrea K. Weber, Larry B. Barber, Denis R. LeBlanc, Elsie M. Sunderland, Chad D. VecitisContaminants of emerging concern in the Great Lakes Basin: A report on sediment, water, and fish tissue chemistry collected in 2010-2012
Despite being detected at low levels in surface waters and sediments across the United States, contaminants of emerging concern (CECs) in the Great Lakes Basin are not well characterized in terms of spatial and temporal occurrence. Additionally, although the detrimental effects of exposure to CECs on fish and wildlife have been documented for many CECs in laboratory studies, we do not adequately uAuthorsSteven J. Choy, Mandy L. Annis, JoAnn Banda, Sarah R. Bowman, Mark E. Brigham, Sarah M. Elliott, Daniel J. Gefell, Mark D. Jankowski, Zachary G. Jorgenson, Kathy Lee, Jeremy N. Moore, William A. TuckerOrganic contamination in tree swallow (Tachycineta bicolor) nestlings at United States and binational great Lakes Areas of Concern
Contaminant exposure of tree swallows, Tachycineta bicolor, nesting in 27 Areas of Concern (AOCs) in the Great Lakes basin was assessed from 2010 to 2014 to assist managers and regulators in their assessments of Great Lakes AOCs. Contaminant concentrations in nestlings from AOCs were compared with those in nestlings from nearby non-AOC sites. Polychlorinated biphenyl (PCB) and polybrominated dipheAuthorsThomas W. Custer, Christine M. Custer, Paul Dummer, Diana R. Goldberg, J. Christian Franson, Richard A. Erickson - News
News stories associated with USGS PFAS studies: