Per- and polyfluoroalkyl substances (PFAS) were detected at low levels in treated drinking water samples from residential taps in the Greater Chicago Area. This study is part of a larger approach to provide an understanding of contaminant mixtures in residential tap water across the Nation including underserved communities in rural, urban, and tribal areas.
Due to the wide variety of uses and environmental persistence, per- and polyfluoroalkyl substances (PFAS) have been found in ambient and drinking water resources, air, soils, and in humans throughout the Nation. Previous science has shown that human exposure to PFAS typically occurs through ingestion of drinking water and food resources in addition to exposure through inhalation of air and dust.
As a component of ongoing research with a coalition of partners, including the U.S. Geological Survey, U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Colorado School of Mines, University of Illinois Chicago, and University of South Carolina, water was collected from the taps of 45 Chicago-area residences and analyzed for 39 per/polyfluoroalkyl substances (PFAS) as part of a complete suite of 540 organic and 35 inorganic chemicals contaminants. This pilot study in the Chicago area complements a 2016 reconnaissance study of 12 business and 13 residential tapwaters in 11 states throughout the United States.
As a reflection of the efficacy of water treatment by the Chicago area drinking water facilities, no Federal drinking water standards were exceeded in any sample collected and 90 percent of organic chemicals analyzed were not detected in treated tapwater samples. Consistent with previous findings from a reconnaissance study in homes and businesses throughout the United States, low-level concentrations of 11 PFASs were detected in greater than 95 percent of the treated tap water samples collected in this study. The U.S. Environmental Protection Agency 70 nanogram per liter advisory was not exceeded in any sample.
While the results of this study emphasize the high quality and effective treatment of the drinking water in the area sampled, the results also demonstrate the potential for human exposure to low concentrations of chemical mixtures that are not commonly monitored or assessed at the point of exposure (tapwater). Although beyond the scope of this investigation, this study reveals a potential data gap in drinking water exposure assessments potentially needed for public health and for epidemiological and other researchers studying pathologic and toxicologic disease. The study results also provide information about sources and potential changes in contaminants as water moves from Lake Michigan to residential taps, including incoming contaminants that may be in the untreated source waters, chemical additions or removals through the treatment process, and changes through infrastructure and plumbing carrying treated water to tap.
This research is designed to support decision makers focused on strategies to reduce human exposure and maintain the safety of U.S. drinking water supplies. Although water purveyors consistently monitor more than 100 chemical and microbial contaminants as part of compliance requirements under the Safe Drinking Water Act, there is a recognized lack of comprehensive data on other known, or suspected, contaminant mixtures such as PFAS in drinking water at the point of exposure in residences. This study continues to be a focus for the U.S. Geological Survey’s Environmental Health Program in the Ecosystems Mission Area that studies contaminants and pathogens in water resources from their sources through watersheds, aquifers, and infrastructure to human and wildlife exposures.
This research was funded by the U.S. Geological Survey’s Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology) in cooperation with the U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Colorado School of Mines, University of Illinois Chicago, and University of South Carolina.
See below for related Ssience
Per-and Polyfluoroalkyl Substances (PFAS) Integrated Science Team
U.S. Geological Survey Per- and Polyfluoroalkyl Substances Science Strategy Identifies Science Gaps and Opportunities
Per- and Polyfluoroalkyl Substances (PFAS) in Residential Tap Water: Source-to-Tap Science for Underserved Communities
Mixtures of Organic and Inorganic Chemicals Characterized in Water from the Taps of Residences in the Greater Chicago Area— Science to Understand Contaminant Exposures in Drinking Water
Per- and Polyfluoroalkyl Substances (PFASs) detected in Source Waters and Treated Public Water Supplies
Study Highlights the Complexity of Chemical Mixtures in United States Streams
Understanding Chemical and Microbial Contaminants in Public Drinking Water
Target-Chemical Concentration Results for Assessment of Mixed-Organic/Inorganic Chemical and Biological Exposures in North Dakota and South Dakota Tapwater, 2019
Inorganic Concentration Results for Assessment of Mixed Organic/Inorganic Chemical and Biological Exposures in North Dakota and South Dakota Tapwater, 2019
Target-Chemical Concentration Results of Mixed-Organic/Inorganic Chemical Exposures in Puerto Rico Tapwater, 2017 to 2018
Target-Chemical Concentration Results of Mixed-Organic/Inorganic Chemical Exposures in Cape Cod, Massachusetts Tapwater, 2018
Mixed Organic and Inorganic Tapwater Results in the Greater Chicago Area, USA, 2017-2019
Occurrence and Concentrations of Trace Elements in Discrete Tapwater Samples Collected in Chicago, Illinois and East Chicago, Indiana, 2017
Target-Chemical Concentrations, Exposure Activity Ratios, and Bioassay Results for Assessment of Mixed-Organic/Inorganic-Chemical Exposure in USA Tapwater, 2016
Below are publications associated with this project.
Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
Integrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Pilot-scale expanded assessment of inorganic and organic tapwater exposures and predicted effects in Puerto Rico, USA
Public and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA
Mixed organic and inorganic tapwater exposures and potential effects in greater Chicago area, USA
Reconnaissance of mixed organic and inorganic chemicals in private and public supply tapwaters at selected residential and workplace sites in the United States
Safe drinking water at the point-of-use (tapwater, TW) is a United States public health priority. Multiple lines of evidence were used to evaluate potential human health concerns of 482 organics and 19 inorganics in TW from 13 (7 public supply, 6 private well self-supply) home and 12 (public supply) workplace locations in 11 states. Only uranium (61.9 μg L–1, private well) exceeded a National Prim
Methods used for the collection and analysis of chemical and biological data for the Tapwater Exposure Study, United States, 2016–17
Concentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017
- Overview
Per- and polyfluoroalkyl substances (PFAS) were detected at low levels in treated drinking water samples from residential taps in the Greater Chicago Area. This study is part of a larger approach to provide an understanding of contaminant mixtures in residential tap water across the Nation including underserved communities in rural, urban, and tribal areas.
Due to the wide variety of uses and environmental persistence, per- and polyfluoroalkyl substances (PFAS) have been found in ambient and drinking water resources, air, soils, and in humans throughout the Nation. Previous science has shown that human exposure to PFAS typically occurs through ingestion of drinking water and food resources in addition to exposure through inhalation of air and dust.
As a component of ongoing research with a coalition of partners, including the U.S. Geological Survey, U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Colorado School of Mines, University of Illinois Chicago, and University of South Carolina, water was collected from the taps of 45 Chicago-area residences and analyzed for 39 per/polyfluoroalkyl substances (PFAS) as part of a complete suite of 540 organic and 35 inorganic chemicals contaminants. This pilot study in the Chicago area complements a 2016 reconnaissance study of 12 business and 13 residential tapwaters in 11 states throughout the United States.
As a reflection of the efficacy of water treatment by the Chicago area drinking water facilities, no Federal drinking water standards were exceeded in any sample collected and 90 percent of organic chemicals analyzed were not detected in treated tapwater samples. Consistent with previous findings from a reconnaissance study in homes and businesses throughout the United States, low-level concentrations of 11 PFASs were detected in greater than 95 percent of the treated tap water samples collected in this study. The U.S. Environmental Protection Agency 70 nanogram per liter advisory was not exceeded in any sample.
U.S. Geological Survey scientist collecting a water sample from a home faucet for analyses of inorganic and organic chemicals. They use an integrated approach to understand drinking water from its sources, through watersheds, aquifers, and infrastructure to tap water where human exposure could occur. (Credit: U. S. Geological Survey. Public domain.) While the results of this study emphasize the high quality and effective treatment of the drinking water in the area sampled, the results also demonstrate the potential for human exposure to low concentrations of chemical mixtures that are not commonly monitored or assessed at the point of exposure (tapwater). Although beyond the scope of this investigation, this study reveals a potential data gap in drinking water exposure assessments potentially needed for public health and for epidemiological and other researchers studying pathologic and toxicologic disease. The study results also provide information about sources and potential changes in contaminants as water moves from Lake Michigan to residential taps, including incoming contaminants that may be in the untreated source waters, chemical additions or removals through the treatment process, and changes through infrastructure and plumbing carrying treated water to tap.
This research is designed to support decision makers focused on strategies to reduce human exposure and maintain the safety of U.S. drinking water supplies. Although water purveyors consistently monitor more than 100 chemical and microbial contaminants as part of compliance requirements under the Safe Drinking Water Act, there is a recognized lack of comprehensive data on other known, or suspected, contaminant mixtures such as PFAS in drinking water at the point of exposure in residences. This study continues to be a focus for the U.S. Geological Survey’s Environmental Health Program in the Ecosystems Mission Area that studies contaminants and pathogens in water resources from their sources through watersheds, aquifers, and infrastructure to human and wildlife exposures.
This research was funded by the U.S. Geological Survey’s Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology) in cooperation with the U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Colorado School of Mines, University of Illinois Chicago, and University of South Carolina.
- Science
See below for related Ssience
Per-and Polyfluoroalkyl Substances (PFAS) Integrated Science Team
Increasing scientific and public awareness of the widespread distribution of per- and poly-fluoroalkyl substances (PFAS) in U.S. drinking-water supplies, aquatic and terrestrial ecosystems, wildlife, and humans has raised many public health and resource management questions that U.S. Geological Survey's (USGS) science can inform. The USGS Environmental Health Program's PFAS Integrated Science Team...U.S. Geological Survey Per- and Polyfluoroalkyl Substances Science Strategy Identifies Science Gaps and Opportunities
USGS recently (2022) released a strategic vision document that identifies science gaps and opportunities for per- and polyfluoroalkyl substances (PFAS) monitoring, assessment, and research activities (sampling protocols and analytical methods, environmental sources and source apportionment, environmental occurrence, environmental fate and transport, human and wildlife exposure routes...Per- and Polyfluoroalkyl Substances (PFAS) in Residential Tap Water: Source-to-Tap Science for Underserved Communities
Per- and polyfluoroalkyl substances (PFAS) were detected at low levels in treated drinking water samples from residential taps in the Greater Chicago Area. This study is part of a larger approach to provide an understanding of contaminant mixtures in residential tap water across the Nation including underserved communities in rural, urban, and tribal areas.Mixtures of Organic and Inorganic Chemicals Characterized in Water from the Taps of Residences in the Greater Chicago Area— Science to Understand Contaminant Exposures in Drinking Water
As a component of ongoing research with a coalition of partners, including the U.S. Geological Survey U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Colorado School of Mines, University of Illinois Chicago, and University of South Carolina, water was collected from the taps of 45 Chicago-area residences and analyzed for 540 organic and 35 inorganic...Per- and Polyfluoroalkyl Substances (PFASs) detected in Source Waters and Treated Public Water Supplies
This study, which measured 17 per- and polyfuoroalkyl substances (PFASs) in source and treated public water supplies from 25 drinking water facilities as part of a broader study of contaminants in drinking water across the United States, reports that PFASs were detected in all source water and public water supply samples collected. One sample exceeded the current U.S. Environmental Protection...Study Highlights the Complexity of Chemical Mixtures in United States Streams
A new study highlights the complexity of chemical mixtures in streams and advances the understanding of wildlife and human exposure to complex chemical mixtures.Understanding Chemical and Microbial Contaminants in Public Drinking Water
Collaborative joint agency study provides nationally consistent and rigorously quality-assured datasets on a wide range of chemical and microbial contaminants present in source and treated public drinking water supplies. Tap water was not analyzed in this study. - Data
Target-Chemical Concentration Results for Assessment of Mixed-Organic/Inorganic Chemical and Biological Exposures in North Dakota and South Dakota Tapwater, 2019
Concentration and quality assurance results for organic compounds and bioassay endocrine activity results analyzed at the U.S. Geological Survey National Water Quality Laboratory, Denver, Colorado, Organic Chemistry Research Laboratory, Sacramento, California, the Organic Geochemistry Research Laboratory, Lawrence, Kansas, and the U.S. Environmental Protection Agency, Office of Research and DeveloInorganic Concentration Results for Assessment of Mixed Organic/Inorganic Chemical and Biological Exposures in North Dakota and South Dakota Tapwater, 2019
This data set reports results for inorganic constituents analyzed at the Redox Chemistry Laboratory in Boulder, Colorado, for the 2019 tapwater study conducted in North Dakota and South Dakota, USA. This project is part of the U.S. Geological Survey, Ecosystems Mission Area, Environmental Health Water and Wastewater Infrastructure Program.Target-Chemical Concentration Results of Mixed-Organic/Inorganic Chemical Exposures in Puerto Rico Tapwater, 2017 to 2018
This dataset provides the water-quality results for organic and inorganic concentrations analyzed from samples collected at domestic and commercial tapwater faucets and one spring, sourced in Puerto Rico. Samples were collected in October, 2017 and August and December, 2018 from 19 locations. Samples were analyzed at various U.S. Geological Survey laboratories: the National Water Quality LaboratorTarget-Chemical Concentration Results of Mixed-Organic/Inorganic Chemical Exposures in Cape Cod, Massachusetts Tapwater, 2018
This dataset provides the water-quality results for organic and inorganic concentrations analyzed from samples collected at residential tapwater faucets, sourced from private drinking water wells in Cape Cod, Massachusetts. Samples were collected in July and August, 2018 from 20 locations. Samples were analyzed at various U.S. Geological Survey laboratories: the National Water Quality Laboratory iMixed Organic and Inorganic Tapwater Results in the Greater Chicago Area, USA, 2017-2019
This data set contains the result for inorganic constituents and organic compounds collected from tapwater locations, as well as water filtration plants, in East Chicago, Indiana, and Chicago, Illinois in 2017. Additionally quality assurance data collected was summarized. Residential samples collected were done so directly from residential kitchen taps (faucets) as is, it was noted if a point-of-uOccurrence and Concentrations of Trace Elements in Discrete Tapwater Samples Collected in Chicago, Illinois and East Chicago, Indiana, 2017
This dataset contains the trace element concentration results for samples collected from tapwater sites in East Chicago, Indiana, August-September, 2017, and Chicago, Illinois, July-December, 2017. Samples were collected one time, from 45 private residences and associated drinking water plants and source water locations. Water-quality samples were analyzed at two U.S. Geological Survey laboratorieTarget-Chemical Concentrations, Exposure Activity Ratios, and Bioassay Results for Assessment of Mixed-Organic/Inorganic-Chemical Exposure in USA Tapwater, 2016
Chemical and biological concentration results, quality assurance and quality control and statistical summaries from 26 tapwater samples, collected from paired residential and work place sites in 11 states in 2016. Samples were analylzed at U.S. Geological Survey and U.S. Environmental Protection Agency laboratories. - Publications
Below are publications associated with this project.
Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
Integrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Concerns related to perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sources of drinking water and in natural and engineered environments have captured national attention over the last few decades. This report provides an overview of the science gaps that exist in the fields of study related to PFAS that are relevant to the U.S. Geological Survey mission and identifies opportunities where tPilot-scale expanded assessment of inorganic and organic tapwater exposures and predicted effects in Puerto Rico, USA
A pilot-scale expanded target assessment of mixtures of inorganic and organic contaminants in point-of-consumption drinking water (tapwater, TW) was conducted in Puerto Rico (PR) to continue to inform TW exposures and corresponding estimations of cumulative human-health risks across the US. In August 2018, a spatial synoptic pilot assessment of than 524 organic, 37 inorganic, and select microbioloPublic and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA
BackgroundHumans are primary drivers of environmental contamination worldwide, including in drinking-water resources. In the United States (US), federal and state agencies regulate and monitor public-supply drinking water while private-supply monitoring is rare; the current lack of directly comparable information on contaminant-mixture exposures and risks between private- and public-supplies underByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Eastern Ecological Science Center, New England Water Science Center, New Jersey Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, National Water Quality LaboratoryMixed organic and inorganic tapwater exposures and potential effects in greater Chicago area, USA
Safe drinking water at the point of use (tapwater, TW) is a public-health priority. TW exposures and potential human-health concerns of 540 organics and 35 inorganics were assessed in 45 Chicago area United States (US) homes in 2017. No US Environmental Protection Agency (EPA) enforceable Maximum Contaminant Level(s) (MCL) were exceeded in any residential or water treatment plant (WTP) pre-distribReconnaissance of mixed organic and inorganic chemicals in private and public supply tapwaters at selected residential and workplace sites in the United States
Safe drinking water at the point-of-use (tapwater, TW) is a United States public health priority. Multiple lines of evidence were used to evaluate potential human health concerns of 482 organics and 19 inorganics in TW from 13 (7 public supply, 6 private well self-supply) home and 12 (public supply) workplace locations in 11 states. Only uranium (61.9 μg L–1, private well) exceeded a National Prim
ByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Central Midwest Water Science Center, Colorado Water Science Center, Eastern Ecological Science Center, Kansas Water Science Center, Michigan-Ohio Water Science Center, New Jersey Water Science Center, Oregon Water Science Center, South Atlantic Water Science Center (SAWSC), St. Petersburg Coastal and Marine Science Center, Upper Midwest Environmental Sciences Center, Upper Midwest Water Science Center, National Water Quality LaboratoryMethods used for the collection and analysis of chemical and biological data for the Tapwater Exposure Study, United States, 2016–17
In 2016, the U.S. Geological Survey (USGS) Environmental Health Mission Area, initiated the Tapwater Exposure Study as part of an infrastructure project to assess human exposure to potential threats from complex mixtures of contaminants. In the pilot phase (2016), samples were collected from 11 States throughout the United States, and in the second phase (2017), the study focused on the Greater ChConcentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017
The U.S. Geological Survey (USGS) Environmental Health Mission Area (EHMA) is providing comprehensive science on sources, movement, and transformation of contaminants and pathogens in watershed and aquifer drinking-water supplies and in built water and wastewater infrastructure (referred to as the USGS Water and Wastewater Infrastructure project) in the Greater Chicago Area and elsewhere in the Un